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Procter & Gamble
Fabric and Home Care Division
Ivorydale Technical Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS # CT# FH/H/2002/JEJW-5EWHYT Issue Date: 01/29/03
CT# FH/H/2002/JEJW-5EWFHK
CT#FH/H/2002/RBRW-59CJMH(S)
CT#FH/H/2002/PTPM-5BNMG7
SECTION I - CHEMICAL PRODUCT
Identity: Liquid Laundry Detergent
Brands: TIDE (All variations)
Hazard Rating: 1 Health: 1 4=EXTREME
Flammability: 1 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
Emergency Telephone Number: 24hr P&G Operator - 1-800-879-8433 or call Local Poison Control Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Biodegradable surfactants (anionic and nonionic) and enzymes.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common CAS No. Recommended Limits Composition LD50/LC50
Chemical
Name Range
Name
ACGIH TWA: 1880 mg/m3
Ethyl alcohol Ethanol 64-17-5 1-5% NA
OSHA PEL & TWA: 1900
mg/m3
ACGIH TWA: 5mg/m3
Sodium borate Borax 1330-43-4 1 鈥? 5% NA
NA
Ethanolamin 141-43-5 0.5 鈥? 1.5%
ACGIH TWA: 7.5 mg/m3
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Aminoethanol ACGIH STEL: 15 mg/m3
OSHA PEL: 6 mg/m3
OSHA TWA: 8 mg/m3
OSHA STEL: 15 mg/m3
SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: May cause transient gastrointestinal irritation.
Eye Contact: May cause mild, transient irritation.
Inhalation: Transient irritation with prolonged exposure to concentrated material.
Signs and Symptoms of Exposure:
Ingestion: May result in nausea, vomiting, and/or diarrhea.
Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness.
Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin.
TIDE LIQUID LAUNDRY DETERGENT MSDS (Continued) Page 2 of
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SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion: Drink a glassful of water.
Eye Contact: Flush with water for 10 to 15 minutes.
Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change
clothes.
If symptoms persist or reoccur, seek medical attention.
Other: Consumer product package has a caution statement: "CAUTION: Eye irritant. Harmful if swallowed.
KEEP OUT OF REACH OF CHILDREN. If swallowed, give a glassful of water. Call a physician. In case of
eye contact, flush with water."
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): 铮?140掳F PM CC Explosive Limits: LEL: N/A UEL: N/A
Extinguishing Media: CO2, water
Special Fire Fighting Procedures:. None.
Unusual Fire Hazards: None. This product has a flash point above 150掳F. It is an aqueous solution containing
ethyl alcohol and it does not sustain combustion.
Conditions to Avoid: None
Stability Unstable:
Stable: X
Incompatibility (Materials to Avoid): None known
Hazardous Decomposition/By Products: None known
Conditions to Avoid: None
Hazardous Polymerization: May Occur:
Will Not Occur: X
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL
REGULATIONS. Small or household quantities may be disposed of in refuse or in sewer. First check with your
local water treatment plant. For larger quantities, incineration is preferred. Do not landfill.
Steps To Be Taken in Case Material is Released or Spilled: Flush small or household quantities down
acceptable sewer (contains biodegradable surfactants). Prevent spills from reaching a waterway. Sorbents may be
used.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: No unusual precautions necessary.
Other Precautions: None
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TIDE LIQUID LAUNDRY DETERGENT MSDS (Continued) Page 3 of 4
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal use.
Ventilation Local Exhaust: None required with normal consumer use. Special: None
Mechanical (General): Normal/general dilution ventilation is acceptable. Other: None
Eye Protection: None required with normal consumer use.
Industrial Setting: If a splash is likely, chemical goggles may be needed.
Protective Gloves: None required with normal use.
Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact.
Other Protective Equipment: None required with normal use.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point 掳 F: 205-207潞F Specific Gravity (H2O=1): 1.060 to 1.080
Vapor Pressure (mm Hg): <29.4 Percent Volatile by Volume (%): 60.99%-61.66%
Vapor Density (Air=1): Unknown Evaporation Rate (nBuOAc=1): Unknown
Odor Threshold: N/A Freezing Point: N/A
Coefficient of Water/Oil Distribution: N/A pH (10% solution): 8.1 to 8.5
Scooped Density: N/A Solubility in Water: Completely soluble.
Appearance and Odor: Ultra Tide High Efficiency Reserve Alkalinity: N/A
and Ultra Tide Free are amber in color. Tide 鈥淒eep
Clean鈥? and Tide w/Bleach Alternative ColorSafe
Bleaching Action are blue in color. All Liquid Tide
products are perfumed, except for Ultra Tide Free
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None
Materials to Avoid: None
Hazardous Decomposition Products: None known
Other Recommendations: None
SECTION XI - TOXICOLOGICAL INFORMATION
SECTION XII - ECOLOGICAL INFORMATION
Based on ecotoxicity and fate data for the individual ingredients in this specific formulation and for related
consumer household cleaning product formulations, it is expected that this product would exhibit a non-hazardous
order of toxicity at relevant environmental concentrations.
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TIDE LIQUID LAUNDRY DETERGENT MSDS (Continued) Page 4 of 4
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Disposal is to be performed in compliance with all Federal, state and local regulations.
Small or household quantities may be disposed of in refuse or in sewer. First check with your local water
treatment plant. For larger quantities, incineration is preferred. Do not landfill.
SECTION XIV - TRANSPORT INFORMATION
The finished product is non-hazardous under DOT.
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURs) under TSCA 搂5.
No components of Tide are subject to California Proposition 65.
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified
with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information
required by the Canadian Products Regulation.
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage
to any property resulting from misuse of the controlled product.
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